CobaltMaghrebV1, Main, Exploration, bibRecord, 000872

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

Identifieur interne : 000872 ( Main/Exploration ); précédent : 000871; suivant : 000873

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

Auteurs : Francesco Capitelli [Italie] ; Brahim El Bali [Maroc] ; Rachid Essehli [Maroc] ; Mohammed Lachkar [Maroc] ; Veronica Valentini [Italie] ; Giorgio Mattei [Italie] ; Jan Taraba [République tchèque] ; Zdirak Zak [République tchèque]

Source :

Zeitschrift für Kristallographie [ 0044-2968 ] ; 2006.

RBID : Pascal:06-0526554

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Mode vibration, Liaison hydrogène, Spectre Raman, Spectre IR, Spectre transformée Fourier, Diffraction RX, Structure cristalline, Ethylène, Ammonium phosphate, Cristal centrosymétrique, Matériau hybride, Réseau triclinique, Cobalt phosphate, Nickel phosphate, 6166F.

English descriptors

KwdEn :
- Ammonium phosphates, Centrosymmetrical crystals, Cobalt phosphates, Crystal structure, Ethylene, Experimental study, Fourier transform spectra, Hybrid material, Hydrogen bonds, Infrared spectra, Nickel phosphates, Raman spectra, Triclinic lattices, Vibrational modes, XRD.

Abstract

New ethylenediammonium diphosphates (NH₃(CH₂)₂NH₃)₂[Me(HP₂O₇)₂ . 2 H₂O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å³ (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å³ (2). The three-dimensional network is built up by discrete Me(HP₂O₇)₂ . 2 H₂O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.

Affiliations:

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Le document en format XML

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(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy</title>
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<author><name sortKey="Taraba, Jan" sort="Taraba, Jan" uniqKey="Taraba J" first="Jan" last="Taraba">Jan Taraba</name>
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<author><name sortKey="Zak, Zdirak" sort="Zak, Zdirak" uniqKey="Zak Z" first="Zdirak" last="Zak">Zdirak Zak</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">New isostructural ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy</title>
<author><name sortKey="Capitelli, Francesco" sort="Capitelli, Francesco" uniqKey="Capitelli F" first="Francesco" last="Capitelli">Francesco Capitelli</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Istituto di Cristallografia (IC-CNR), sezione di Bari, Via Amendola 122/o</s1>
<s2>70126 Bari</s2>
<s3>ITA</s3>
<sZ>1 aut.</sZ>
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<wicri:noRegion>70126 Bari</wicri:noRegion>
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</author>
<author><name sortKey="El Bali, Brahim" sort="El Bali, Brahim" uniqKey="El Bali B" first="Brahim" last="El Bali">Brahim El Bali</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
<s2>30000 Fès</s2>
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<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Maroc</country>
<wicri:noRegion>30000 Fès</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Essehli, Rachid" sort="Essehli, Rachid" uniqKey="Essehli R" first="Rachid" last="Essehli">Rachid Essehli</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
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</author>
<author><name sortKey="Lachkar, Mohammed" sort="Lachkar, Mohammed" uniqKey="Lachkar M" first="Mohammed" last="Lachkar">Mohammed Lachkar</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire d'Analyses, d'Essais et d'Environnement (LAEE), Département de Chimie, Faculté des Sciences Dhar Mehraz, BP 1796 Atlas</s1>
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<author><name sortKey="Valentini, Veronica" sort="Valentini, Veronica" uniqKey="Valentini V" first="Veronica" last="Valentini">Veronica Valentini</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10</s1>
<s2>00016 Monterotondo Stazione (Roma)</s2>
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<sZ>5 aut.</sZ>
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<country>Italie</country>
<wicri:noRegion>00016 Monterotondo Stazione (Roma)</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Mattei, Giorgio" sort="Mattei, Giorgio" uniqKey="Mattei G" first="Giorgio" last="Mattei">Giorgio Mattei</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Istituto dei Sistemi Complessi (ISC-CNR), sezione di Montelibretti, Area della ricerca di Roma-Montelibretti, Via Salaria km 29,300 - C.P. 10</s1>
<s2>00016 Monterotondo Stazione (Roma)</s2>
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<country>Italie</country>
<wicri:noRegion>00016 Monterotondo Stazione (Roma)</wicri:noRegion>
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<author><name sortKey="Taraba, Jan" sort="Taraba, Jan" uniqKey="Taraba J" first="Jan" last="Taraba">Jan Taraba</name>
<affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Department of Inorganic Chemistry, Masaryk University, Kotlárska 2</s1>
<s2>61137 Brno</s2>
<s3>CZE</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>République tchèque</country>
<placeName><settlement type="city">Brno</settlement>
<region>Moravie</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Zak, Zdirak" sort="Zak, Zdirak" uniqKey="Zak Z" first="Zdirak" last="Zak">Zdirak Zak</name>
<affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Department of Inorganic Chemistry, Masaryk University, Kotlárska 2</s1>
<s2>61137 Brno</s2>
<s3>CZE</s3>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>République tchèque</country>
<placeName><settlement type="city">Brno</settlement>
<region>Moravie</region>
</placeName>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Zeitschrift für Kristallographie</title>
<title level="j" type="abbreviated">Z. Kristallogr.</title>
<idno type="ISSN">0044-2968</idno>
<imprint><date when="2006">2006</date>
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<idno type="ISSN">0044-2968</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Ammonium phosphates</term>
<term>Centrosymmetrical crystals</term>
<term>Cobalt phosphates</term>
<term>Crystal structure</term>
<term>Ethylene</term>
<term>Experimental study</term>
<term>Fourier transform spectra</term>
<term>Hybrid material</term>
<term>Hydrogen bonds</term>
<term>Infrared spectra</term>
<term>Nickel phosphates</term>
<term>Raman spectra</term>
<term>Triclinic lattices</term>
<term>Vibrational modes</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Mode vibration</term>
<term>Liaison hydrogène</term>
<term>Spectre Raman</term>
<term>Spectre IR</term>
<term>Spectre transformée Fourier</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Ethylène</term>
<term>Ammonium phosphate</term>
<term>Cristal centrosymétrique</term>
<term>Matériau hybride</term>
<term>Réseau triclinique</term>
<term>Cobalt phosphate</term>
<term>Nickel phosphate</term>
<term>6166F</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">New ethylenediammonium diphosphates (NH<sub>3</sub>
(CH<sub>2</sub>
)<sub>2</sub>
NH<sub>3</sub>
)<sub>2</sub>
[Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O] [Me = Co (1), Ni (2)] have been synthesized and investigated by single-crystal X-ray diffractometry. The two structures resulted to be isostructural within triclinic space group P1. The unit-cell parameters are: a = 7.5211(6) Å, b = 7.5574(3) Å, c = 9.7689(7) Å, α = 103.6(1)°, β = 111.14(1)°, y = 98.04(1)°, V = 486.9(1) Å<sup>3</sup>
 (1) and a = 7.4631(15) Å, b = 7.5274(12) Å, c = 9.743(3) Å, a = 104.28(2)°, β = 110.75(2)°, y = 97.50(2)°, V = 481.4(2) Å<sup>3</sup>
 (2). The three-dimensional network is built up by discrete Me(HP<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
 . 2 H<sub>2</sub>
O moieties, which, via strong O-H... O bonds, form layers parallel to ab plane. Ethylenediammonium groups are located between such layers, stabilizing the framework via N-H... O bonds. The hydrogendiphosphate group presents bent eclipsed conformation, while the Me ion lies on inversion centre. The structural data, as the bent POP configuration, have been confirmed by the Raman and infrared spectra of the title compounds. In particular, the non-coincidence between the infrared and Raman bands supports the centrosymmetric structure of the investigated crystals.</div>
</front>
</TEI>
<affiliations><list><country><li>Italie</li>
<li>Maroc</li>
<li>République tchèque</li>
</country>
<region><li>Moravie</li>
</region>
<settlement><li>Brno</li>
</settlement>
</list>
<tree><country name="Italie"><noRegion><name sortKey="Capitelli, Francesco" sort="Capitelli, Francesco" uniqKey="Capitelli F" first="Francesco" last="Capitelli">Francesco Capitelli</name>
</noRegion>
<name sortKey="Mattei, Giorgio" sort="Mattei, Giorgio" uniqKey="Mattei G" first="Giorgio" last="Mattei">Giorgio Mattei</name>
<name sortKey="Valentini, Veronica" sort="Valentini, Veronica" uniqKey="Valentini V" first="Veronica" last="Valentini">Veronica Valentini</name>
</country>
<country name="Maroc"><noRegion><name sortKey="El Bali, Brahim" sort="El Bali, Brahim" uniqKey="El Bali B" first="Brahim" last="El Bali">Brahim El Bali</name>
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<name sortKey="Essehli, Rachid" sort="Essehli, Rachid" uniqKey="Essehli R" first="Rachid" last="Essehli">Rachid Essehli</name>
<name sortKey="Lachkar, Mohammed" sort="Lachkar, Mohammed" uniqKey="Lachkar M" first="Mohammed" last="Lachkar">Mohammed Lachkar</name>
</country>
<country name="République tchèque"><region name="Moravie"><name sortKey="Taraba, Jan" sort="Taraba, Jan" uniqKey="Taraba J" first="Jan" last="Taraba">Jan Taraba</name>
</region>
<name sortKey="Zak, Zdirak" sort="Zak, Zdirak" uniqKey="Zak Z" first="Zdirak" last="Zak">Zdirak Zak</name>
</country>
</tree>
</affiliations>
</record>

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New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

New isostructural ethylenediammonium diphosphates (NH3(CH2)2NH3)2[Me(HP2O7)2 . 2 H2O] [Me = Co, Ni] : X-ray crystal structure and vibrational spectroscopy

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Descripteurs français

English descriptors

Abstract

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Le document en format XML

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Pour mettre un lien sur cette page dans le réseau Wicri